Electronic Structure and Reactivity of Mononuclear Nonheme Iron-Peroxo Complexes as a Biomimetic Model of Rieske Oxygenases: Ring Size Effects of Macrocyclic LigandsJournal of the American Chemical Society, 2024, v.146 no.1, 250-262
A Manganese Compound I Model with a High Reactivity in the Oxidation of Organic Substrates and WaterJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, v.145 no.15, 8319-8325
Generation, Spectroscopic Characterization, and Computational Analysis of a Six-Coordinate Cobalt(III)-Imidyl Complex with an Unusual S = 3/2 Ground State that Promotes N-Group and Hydrogen Atom-Transfer Reactions with Exogenous SubstratesJournal of the American Chemical Society, 2023, v.145 no.48, 26106-26121
Seeing the cis-Dihydroxylating Intermediate: A Mononuclear Nonheme Iron-Peroxo Complex in cis-Dihydroxylation Reactions Modeling Rieske DioxygenasesJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, v.145 no.8, 4389-4393
A Contrasting Effect of Acid in Electron Transfer, Oxygen Atom Transfer, and Hydrogen Atom Transfer Reactions of a Nickel(III) ComplexInorganic Chemistry, 2022, v.61 no.49, 19735-19747
Preparation and Characterization of a Formally NiIV-Oxo Complex with a Triplet Ground State and Application in Oxidation ReactionsJournal of the American Chemical Society, 2022, v.144 no.49, 22698-22712
A Highly Reactive Chromium(V)-Oxo TAML Cation Radical Complex in Electron Transfer and Oxygen Atom Transfer ReactionsACS CATALYSIS, 2021, v.11 no.5, 2889-2901
A Mononuclear Non-heme Iron(III)-Peroxo Complex with an Unprecedented High O-O Stretch and Electrophilic ReactivityJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, v.143 no.38, 15556-15561
Deeper Understanding of Mononuclear Manganese(IV)-Oxo Binding Bronsted and Lewis Acids and the Manganese(IV)-Hydroxide ComplexINORGANIC CHEMISTRY, 2021, v.60 no.22, 16996-17007
Electron-Transfer and Redox Reactivity of High-Valent Iron Imido and Oxo Complexes with the Formal Oxidation States of Five and SixJournal of the American Chemical Society, 2020, v.142 no.8, 3891-3904
Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene ComplexAngewandte Chemie - International Edition, 2020, v.59 no.32, 13581-13585
A High-Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing ReactivityAngewandte Chemie - International Edition, 2019, v.58 no.45, 16124-16129
Redox Reactivity of a Mononuclear Manganese-Oxo Complex Binding Calcium Ion and Other Redox-Inactive Metal IonsJournal of the American Chemical Society, 2019, v.141 no.3, 1324-1336
Tunneling Controls the Reaction Pathway in the Deformylation of Aldehydes by a Nonheme Iron(III)-Hydroperoxo Complex: Hydrogen Atom Abstraction versus Nucleophilic AdditionJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, v.141 no.19, 7675-7679
An amphoteric reactivity of a mixed-valent bis(mu-oxo)dimanganese(III,IV) complex acting as an electrophile and a nucleophileDALTON TRANSACTIONS, 2016, v.45 no.1, 376-383
Mononuclear Nonheme High-Spin Iron(III)-Acylperoxo Complexes in Olefin Epoxidation and Alkane Hydroxylation ReactionsJournal of the American Chemical Society, 2016, v.138 no.7, 2426-2436
Mechanistic insights into the reactions of hydride transfer versus hydrogen atom transfer by a trans-dioxoruthenium(vi) complexDalton Transactions, 2015, v.44 no.16, 7634-7642
Mechanistic insights into the C-H bond activation of hydrocarbons by chromium(IV) oxo and chromium(III) superoxo complexesInorganic Chemistry, 2014, v.53 no.1, 645-652
Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)-peroxo complexesNATURE CHEMISTRY, 2014, v.6 no.10, 934-940
Spectroscopic Capture and Reactivity of a Low-Spin Cobalt(IV)-Oxo Complex Stabilized by Binding Redox-Inactive Metal IonsANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, v.53 no.39, 10403-10407
Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)-Hydroperoxo ComplexJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, v.136 no.35, 12229-12232